I am sure that it would of course give me experience setting up a server environment. Is there a particular book or reference I should have?
I'd have to recommend Mark Minasi's (plus others) 'Mastering Windows Server 2000/2003/2008'. A really good book, everything is very well explained with not just how but why. The 2000 edition can be had for a couple of quid from online bookshops.
Although I don't do servers, I do run a lot VirtualBox for learning on and armed with that book I build a virtual network. I had Windows Server 2003 domain with and Windows 2000 AS DCs, added lots of clients: Vista, XP, Win98, (even Win3.11), Linux, MacOS (System 8.0 via Basilisk).
Lots of fun and very educational.