Your list doesn't actually have anything to do with training. I've never done remote training, but here's how my residential sessions tend to go:
When I set up the appointment, I tell them to make a list of the things they want to learn; I encourage them to play with it ahead of time and figure out what they can (the more they know, the less I need to teach). Not everyone does this; normally they call you after they've tried to play with it and have given up. Sometimes you'll have to explain what the Microsoft account is and help them decide whether they want it or a local account; you may have to set up that account for them. It will all depend on what the person is comfortable doing.
Many times, they assume you'll copy their files and stuff from their old PC to the new PC; make sure you ask if they need that when making the appointment. If it's a laptop you may have to set up the wireless network information.
The first three things people want to know:
1 - How to check email
2 - How to check Facebook
3 - How to turn it off
I begin by showing them the start screen; I explain that it replaced the start menu. Normally I have it boot to the desktop so it's more familiar if they're running 8.1. At the moment I'm not encouraging people to upgrade from 8 to 8.1 (for many reasons). I show them how to adjust tiles and I'll make any adjustments they may want. I recommend they give it a week or two, then if they don't like the start screen I can install a menu (I would do this remotely).
Depending on what they are used to, I'll either set up Outlook, the Mail metro app, or show them that webmail is the same.
If they want a particular web browser, I'll set it up; otherwise I show both the Metro IE (grudgingly; people tend to find it and want to know why it's different) and the desktop IE (except Windows 8.1; IE 11 took three steps backward so I install something else). I set the home page and (if I transferred files) show them their favorites.
I generally use D7 to add power options to the desktop context menu; I then show them that, typing "turn off" or "shut down" at the start screen, or taking the cursor to the right and clicking Settings. Show all three and people will pick what they consider to be the easiest (and possibly remember it). I've seen that some vendors (ie, Acer) may have a utility pinned to the desktop bar and on the start screen.
From here, I show the Windows store, and maybe install the solitaire collection so they see what a purchase does. Then I'll go over the questions the person has about it and do a final review. Unless you're transferring stuff from an old PC it easily fits in an hour.
Show is better than tell, and stepping back to let the person do it is even better. They're more likely to remember what they do than what they see.
