Did you get beyond the video problems with it and this is a new problem? or are things just getting worse?
Beyond what the others have said and without looking into this any further. You could have toasted the CPU by not seating the heatsink correctly or something when you put it back together. That would explain a still working motherboard light but no post.
I have also seen machines power up then quickly shutdown when the 4 pin P4 connector isnt plugged in properly. I have also seen plugs getting hot and burning when they arent making proper contact
such as this.
Again, without seeing the computer and spending time really researching this for you, I am just guessing at the moment.