Oxford Brookes University and other universities that connect to the internet via JANET is blocked from Hotmail. JANET is a shared academic network.
Microsoft is working to resolve the problem but Oxford Brookes has not heard anything back from it.
BT, Yahoo! and Comcast appeared to be blocking email from universities too and a random basis.
Both Microsoft and BT had not responded about this issue. The reason for the apparent block is currently unknown.
Source: The Register

Articles
Blogs
Kits
Forums
Lee
Seen this a lot with smaller networks. The culprit is usually SORBS or some other sloppy dynamic hosts list for spam blocking.